## Abstract Rate constants for the gasβphase reactions of hydroxyl radicals and chlorine atoms with a series of alcohols have been determined by using the relative method. The experiments were performed at 295 Β± 2 K and at 1 atmospheric pressure. The obtained values of the rate constants in units o
Formyl chloride: UV absorption cross sections and rate constants for the reactions with chlorine atom and hydroxyl radical
β Scribed by Libuda, H. G.; Zabel, F.; Fink, E. H.; Becker, K. H.
- Book ID
- 118278906
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 776 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21
## Abstract Rate constants for the gasβphase reactions of hydroxyl radicals and chlorine atoms with aliphatic alcohols and ethers have been determined at 298 Β± 2 K and at a total pressure of 1 atmosphere. The OH radical rate data were obtained using both the absolute technique of pulse radiolysis c
## Abstract A flash photolysis setup coupled to UV absorption spectrometry detection was used to measure the UV absorption spectra of the (CH~3~)~2~(CH~2~O~2~.)CC(O)C(CH~3~)~3~ and (CH~3~)~2~(CH~2~O~2~.)CC(O)CH~3~ radicals between 207 and 290 nm. The selfβreaction rate constants of these radicals w