UV absorption spectrum and self-reaction of cyclohexylperoxy radicals
β Scribed by Rowley, David M.; Lightfoot, Phillip D.; Lesclaux, Robert; Wallington, Timothy J.
- Book ID
- 120601070
- Publisher
- Royal Society of Chemistry
- Year
- 1991
- Tongue
- English
- Weight
- 750 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0956-5000
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π SIMILAR VOLUMES
Neopentyl radicals were produced via the reaction F+ ( CH3)&-r (CH,)sCCH2 t HF, which was initiated by pulse radiolysis of neopentane/SF, gas mixtures at 298 K. The ultraviolet absorption spectrum of neopentyl radicals has been recorded over the wavelength range 220-270 nm. An absorption cross secti
The ultraviolet absorption spectrum of the neopentylperoxy radical, (CH3)3CCH202 (or C5HI1O2), and the kinetics of its self-reaction have been studied in the gas phase using a flash photolysis technique. The room temperature absorption cross-section at 250 nm was determined to be 0 ~~~, , 0 ~( 2 5 0
The ultraviolet absorption spectrum of the chloroethylperoxy radical, CH2ClCH202, and the kinetics of its self-reaction have been studied in the gas phase using a flash photolysis technique. The room temperature absorption cross section at 250 nm was determined to be bc~~ac~,o~ ( 250nm) = ( 3.64 5 0
The ultraviolet absorption spectrum, kinetics, and mechanism of the self reaction of CF3CF202 radicals have been studied in the gas phase a t 295 K. Two techniques were used; pulse radiolysis W absorption to measure the spectrum and kinetics, and long-path length FTIR spectroscopy to identify and qu