## Abstract A rate constant for the reaction of NO~3~ with propene has been determined by an absolute rate technique at room temperature and atmospheric pressure. Experiments were performed in a Pyrex photoreactor coupled to two multiple reflection optical systems interfaced to a FTIR spectrometer
Utilization of the simpler optimization algorithm for the determination of amino acid absolute racemization rate constants
β Scribed by Ron Valcarce; Grant Gill Smith
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 762 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0169-7439
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π SIMILAR VOLUMES
We discuss the performance optimization of the Semi-Implicit Method for Pressure-Linked Equations-Revised (SIMPLER) Picard algorithm for steady incompressible internal ows. We discuss the nonlinear convergence of the Picard iteration as a function of the pressure and scalar potential continuity proj
Rate constants of OH radical reaction with some amino polycarboxylic acids (APCAs) such as EDTA, DTPA, HEDTA, NTA, and HIDA have been determined at different pHs using pulse radiolysis competition kinetics method with thiocyanate as the reference solute. The rate constants varied with pH (possibly d
## Abstract Enantiopure Ξ±βamino acids were converted to 4βsubstituted 2βarylβ and 2βalkylβ5(4__H__)βoxazolones under partial racemization. These nonracemic mixtures were dissolved in CDCl~3~, an equimolar amount of the chiral dirhodium complex $Rh^{\rm (II)}\_{2}$[(__R__)β (+)β MTPA]~4~ (MTPAβH = M