An absolute value of k, of ethyl radicals at 860 f 17°K of 4.5 X l o 9 M-l.sec-' was determined under VLPP conditions, where the value of k,/k," should be about M. Thus k,"(M-'.sec-') -10' 0 at 860°K. An error of as much as a factor of 2 in k, would be surprising, but possible. The value of lO'OM-'
Determination of absolute rate constants for free radical polymerization of ethyl α-fluoroacrylate and characterization of the polymer
✍ Scribed by Yamada, Bunichiro ;Kontani, Takashi ;Yoshioka, Minoru ;Otsu, Takayuki
- Publisher
- John Wiley and Sons
- Year
- 1984
- Weight
- 608 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0360-6376
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