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Determination of the activation rate constants of alkyl halide initiators for atom transfer radical polymerization

โœ Scribed by Atsushi Goto; Takeshi Fukuda


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
53 KB
Volume
20
Category
Article
ISSN
1022-1336

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Determination of the rate constants for
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Using a relative rate method, rate constants for the gas-phase reactions of 2methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO 3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at and total 298 ฯฎ 2 K 740 ฯฎ 5 torr pressure are: ฯช11 3 ฯช1 ฯช1 ฯช18 3 k ฯญ (3.9 ฯฎ 1.