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Using the Power-Law Rate Expression for Assessment of Rate Data and Detection of Infeasible Mechanisms for Reversible Reactions

✍ Scribed by Shacham, Mordechai; Brauner, Neima


Book ID
120928168
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
162 KB
Volume
35
Category
Article
ISSN
0888-5885

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Overwhelming evidence has been previously reported for the existence of the so-called "dimer nucleophile mechanism" in aromatic nucleophilic substitutions by amines in aprotic solvents, for which the most prominent feature is the fourth-order kinetics (third order in amine) that has been observed wi