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Unusual stereoselectivity in the Diels-Alder addition of cyclopentadiene with the bicyclo[2.2.2]octene nucleus

✍ Scribed by Williams, Richard Vaughan; Todime, Murali Mohan Reddy; Enemark, Paul; van der Helm, Dick; Rizvi, Safia Khalil


Book ID
118005055
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
529 KB
Volume
58
Category
Article
ISSN
0022-3263

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Face Selectivity of the Diels-Alder Reac
✍ Macro Avenati; Pierre Vogel 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 598 KB

## Abstract The face selectivity (__endo__‐face __vs. exo__‐face attack onto the exocyclic s‐__cis__‐butadiene moiety) of the [4+2]cycloadditions of 5,6‐bis((D)methylidene)‐2‐bicyclo‐[2.2.2]octene (**11**) to strong dienophiles has been determined in benzene at 25°. It is __ca.__ 95/5, 75/5, 70/30,