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Manifestations of the Alder−Rickert Reaction in the Structures of Bicyclo[2.2.2]octadiene and Bicyclo[2.2.2]octene Derivatives

✍ Scribed by Goh, Yit Wooi; Danczak, Stephen M.; Lim, Tang Kuan; White, Jonathan M.


Book ID
121502896
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
158 KB
Volume
72
Category
Article
ISSN
0022-3263

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The Reaction of Difluorocarbene with Bic
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## Abstract The addition of difluorocarbene to bicyclo[2.2.2]octa‐2,5‐diene gave the __exo__ and __endo__ 1:1 cyclopropane adducts. In contrast to norbornadiene, no __homo__‐1,4 adduct was formed. The adducts were thermally stable under the conditions of their formation and separation (<170°). Howe