## Abstract The behaviour of bicyclo [2.2.2]octaβ2,5βdiene (1) towards perbenzoic acid, 2,4 dinitrophenylsulfenyl chloride and ozone has been studied. In no instance was the formation of a homotricyclene derivative by homoconjugative addition observed. However, the primary formation of homoallylic
The Synthesis of Bicyclo [2,2,2]-2,5-octadiene 1,2
β Scribed by Hine, Jack; Brown, John A.; Zalkow, Leon H.; Gardner, William E.; Hine, Mildred
- Book ID
- 121386167
- Publisher
- American Chemical Society
- Year
- 1955
- Tongue
- English
- Weight
- 668 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract Pure bicycloβ[2,2,2]β2,5βoctadiene (I), m. p. 57Β°, has been prepared (a) by treatment of trimethylβbicycloβ5βoctenylβ2βammonium chloride (IIIa) with phenyllithium, (b) by Hofmann degradation of the corresponding quaternary base IIIc and (c) by thermal decomposition of the Nβoxide of 2βd
## Abstract The addition of difluorocarbene to bicyclo[2.2.2]octaβ2,5βdiene gave the __exo__ and __endo__ 1:1 cyclopropane adducts. In contrast to norbornadiene, no __homo__β1,4 adduct was formed. The adducts were thermally stable under the conditions of their formation and separation (<170Β°). Howe