𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Synthesis of Bicyclo [2,2,2]-2,5-octadiene 1,2

✍ Scribed by Hine, Jack; Brown, John A.; Zalkow, Leon H.; Gardner, William E.; Hine, Mildred


Book ID
121386167
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
668 KB
Volume
77
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Elektrophile Additionen an Bicyclo[2,2,2
✍ A. Gagneux; C. A. Grob πŸ“‚ Article πŸ“… 1959 πŸ› John Wiley and Sons 🌐 German βš– 450 KB πŸ‘ 1 views

## Abstract The behaviour of bicyclo [2.2.2]octa‐2,5‐diene (1) towards perbenzoic acid, 2,4 dinitrophenylsulfenyl chloride and ozone has been studied. In no instance was the formation of a homotricyclene derivative by homoconjugative addition observed. However, the primary formation of homoallylic

Untersuchungen in der Bicyclo-[2,2,2]-oc
✍ C. A. Grob; H. Kny; A. Gagneux πŸ“‚ Article πŸ“… 1957 πŸ› John Wiley and Sons 🌐 German βš– 744 KB

## Abstract Pure bicyclo‐[2,2,2]‐2,5‐octadiene (I), m. p. 57Β°, has been prepared (a) by treatment of trimethyl‐bicyclo‐5‐octenyl‐2‐ammonium chloride (IIIa) with phenyllithium, (b) by Hofmann degradation of the corresponding quaternary base IIIc and (c) by thermal decomposition of the N‐oxide of 2‐d

The Reaction of Difluorocarbene with Bic
✍ Charles W. Jefford; Arlette Delay; Timothy W. Wallace; Ulrich Burger πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 466 KB

## Abstract The addition of difluorocarbene to bicyclo[2.2.2]octa‐2,5‐diene gave the __exo__ and __endo__ 1:1 cyclopropane adducts. In contrast to norbornadiene, no __homo__‐1,4 adduct was formed. The adducts were thermally stable under the conditions of their formation and separation (<170Β°). Howe