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A Facile Diels−Alder Reaction with Benzene: Synthesis of the Bicyclo[2.2.2]octene Skeleton Promoted by Rhenium

✍ Scribed by Chordia, Mahendra D.; Smith, Philip L.; Meiere, Scott H.; Sabat, Michal; Harman, W. Dean


Book ID
127122797
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
40 KB
Volume
123
Category
Article
ISSN
0002-7863

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## Abstract Selective oxidations of bis(tricarbonyliron) complexes of methyl (3,7,8‐trimethylidenebicyclo[2.2.2]oct‐5‐en‐2‐ylidene)methyl ketones **15**–**17** afforded selectively the tricarbonyl {(1__RS__,4__SR__,7__SR__,8__RS__)‐__C__,7,8,__C__‐η‐[methyl (3,7,8‐trimethylidenebicyclo[2.2.2]oct‐5‐