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Synthesis of the bicyclo[6.2.1]undecane ring system by a solvent-free Diels–Alder reaction

✍ Scribed by Beatriz, Adilson; Gomes, Roberto da Silva; Constantino, Mauricio Gomes; da Silva, Gil Valdo José; de Oliveira, Kleber Thiago


Book ID
121425629
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
747 KB
Volume
55
Category
Article
ISSN
0040-4039

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In refluxing decalin P-alkenyl-1-alkoxycarbonyl-1,2\_dihydropyridines undergo an intramolecular Diels-Alder reaction to provide novel polycyclic compounds. The cis-decahydroquinoline ring system can be prepared from the appropriate Diels-Alder product utilizing a ring-opening reverse Mannich reactio