Unusual dimroth rearrangement of an allyl-1,2,4-triazolo[4,3-c]pyrimidine
β Scribed by G. G. Danagulyan; L. G. Saakyan; G. A. Panosyan; G. A. Bulakhov; P. B. Terent'ev; M. G. Zalinyan
- Publisher
- Springer US
- Year
- 1993
- Tongue
- English
- Weight
- 147 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-3122
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## Abstract Some new 1,2,3βtriazolo[4,5β__e__]β1,2,4βtriazolo[3,4β__c__]pyrimidmes were prepared starting from the corresponding 1,2,3βtriazolo[4,5β__d__]pyrimidines __via__ the formation of the 1,2,4βtriazole ring. Thus suitable hydrazino derivatives 6 were condensed with triethyl orthoformate, tr
Derivatives of the new ring system pyrazolo [3,4-d][1,2,3]triazolo[1,5-a]pyrimidine were synthesized from the corresponding angular isomers, through a Dimroth rearrangement, in quantitative yields. Preliminary computational studies demonstrated that this class of compounds could be a good candidate