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Unusual cleavage of adducts of trialkyl phosphites with perfluoromethacrylic acid derivatives

✍ Scribed by I. L. Knunyants; U. Utebaev; E. M. Rokhlin; É. P. Lur'e; E. I. Mysov


Book ID
112437888
Publisher
Springer
Year
1976
Tongue
English
Weight
657 KB
Volume
25
Category
Article
ISSN
1573-9171

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Reactions of N-phthalylamino acid chlori
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Reaction of commercially available trialkyl phosphites with N-phthalylamino acids gave mixtures of seven products, whereas the same reaction carried out with pure triethyl phosphite yielded only the desired 2-(N-phthalylamino)-1-oxoalkanephosphonates. These compounds underwent rearrangement to the s