Reaction of isonitriles with perfluoromethacrylic acid derivatives
β Scribed by E. A. Avetisyan; N. P. Gambaryan
- Book ID
- 112480615
- Publisher
- Springer
- Year
- 1975
- Tongue
- English
- Weight
- 151 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Isonitriles react with low concentrations of carboxylic acids in toluene at 110 Β°C to give N-formylamides in yields generally above 70%. These concentrations can be obtained either by syringe pump addition of a toluene solution of the acid, or by using a suspension of the acid if it has limited solu
Isonitriles react with carbenes to give @-adducts, keteneimines. 1) Further cycloaddition of isonitriles to keteneimines is expected when the substituents of them are aromatic. From this point of view, reaction of several aromatic isonitriles with diazoalkanes as the precursors of carbene was examin