Rotational isomerism in 3-mono-oxygenate
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Philip J. Dawson; Trevor A. Crabb; Roger O. Williams
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Article
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1977
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John Wiley and Sons
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English
⚖ 359 KB
## Abstract The ^1^H n.m.r. spectra of 3‐mono‐oxygenated and 3,7‐dioxygenated __N__‐acetyl‐17‐aza‐D‐homoandrost‐5‐enes show unequal populations of the amide rotational isomers in chloroform‐__d__~1~ solution. The populations are dependent upon the orientation of the C‐7 oxygen substituent but are i