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Unusual cis-trans isomerism in N-acetyl, N‘-methylamide derivatives of syn- and anti-5-methylproline

✍ Scribed by DELANEY, NORMA G. ;MADISON, VINCENT


Book ID
115097866
Publisher
Wiley (Blackwell Publishing)
Year
2009
Tongue
English
Weight
399 KB
Volume
19
Category
Article
ISSN
0367-8377

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Rotational isomerism in 3-mono-oxygenate
✍ Philip J. Dawson; Trevor A. Crabb; Roger O. Williams 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 359 KB

## Abstract The ^1^H n.m.r. spectra of 3‐mono‐oxygenated and 3,7‐dioxygenated __N__‐acetyl‐17‐aza‐D‐homoandrost‐5‐enes show unequal populations of the amide rotational isomers in chloroform‐__d__~1~ solution. The populations are dependent upon the orientation of the C‐7 oxygen substituent but are i