Of the many solvolysis rate studies involving ally1 compounds, only two have examined the effect of extending conjugation. Vernon' has estimated that replacement of a p-methyl group by a phenyl group (1. and 2) increases the rate by a factor of gg. 140. Friedrich and WinsteIn have studied some spiro
โฆ LIBER โฆ
Unsymmetrical allyl cations in the solvolysis of cycloalkenyl 3,5-dinitrobenzoates
โ Scribed by Kenneth B. Wiberg; Takayuki Nakahira
- Book ID
- 104234906
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 204 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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Recently we reprted about the first example of a 1.2-hydride shift durmg the generation of a vrnyl cation, a process well known for trlsubstituted car&mum ions 2) :Thls was obsermildurlng the solvolys~s of cls-and trans-3-cyclop~l-2-propen-2-yl-trifl~~~esulfo~~(tnflate)3! --The 1.2-hydride shLft was