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Vinyl cation rearrangement in the solvolysis of 5α-cholest-1-en-1-yl triflate

✍ Scribed by Giorgio Ortar; Enrico Morera


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
263 KB
Volume
20
Category
Article
ISSN
0040-4039

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Vinyl cations, 22 a 1,2-hydride shift in
✍ Klaus-Peter Jäckel; Michael Hanack 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 137 KB

Recently we reprted about the first example of a 1.2-hydride shift durmg the generation of a vrnyl cation, a process well known for trlsubstituted car&mum ions 2) :Thls was obsermildurlng the solvolys~s of cls-and trans-3-cyclop~l-2-propen-2-yl-trifl~~~esulfo~~(tnflate)3! --The 1.2-hydride shLft was