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Unsaturated Alcohol Esters of the 9,10-Dihydroxystearic Acids. Preparation of Elaidyl Alcohol

โœ Scribed by Swern, Daniel; Jordan, E. F.; Knight, H. B.

Book ID
126834839
Publisher
American Chemical Society
Year
1946
Tongue
English
Weight
256 KB
Volume
68
Category
Article
ISSN
0002-7863

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A series of chiral propargylic alcohols with high enantiomeric excess was prepared by asymmetric dihydroxylation of a,b-unsaturated esters, conversion of the diols to 4-(chloromethyl)-1,3-dioxolane intermediates, and base-induced elimination.