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Unimolecular reactions of isolated organic ions. The importance of ion-dipole interactions

✍ Scribed by Bowen, Richard D.; Williams, Dudley H.


Book ID
126422512
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
601 KB
Volume
102
Category
Article
ISSN
0002-7863

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Unimolecular reactions of isolated organ
✍ Richard D. Bowen; Alex W. Colburn; Peter J. Derrick πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 871 KB

The reactions of metastable CH,-CHCH=bCH, oxonium ions generated by alkyl radical loss from ionized allylic alkenyl methyl ethers are reported aod d i s c d Three main reactions occur, corresponding to expulsion of H,O, C2H,/C0 and CH,O. There is also a very minor amount of C,H, elimination. The mec