Non-concrted unimolecular reactions of ions in the gas-phase: The importance of ion-dipole interactions in carbonium ion isomerizations
β Scribed by Richard D. Bowen; Dudley H. Williams
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 647 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0020-7381
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
The loss of alkanes from ionized aliphatic alkanes, alcohols, ketones, ethers or amines takes place by a 1,2elimination involving a C -C bond cleavage and the specific rearrangement of a hydrogen atom to the incipient radical. This reaction should normally occur within a limited distance between the
The rearrangement of the molecular ions of the isomeric 2-and fmethyl benzofurans (1 and 2), 2H-chromene (3) and 4H-chromene (4) has been studied as a further example of the isomerization of oxygen-heteroaromatic radical cations via a ring expansionlring contraction mechanism well documented for mol