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Catalyzed Isomerizations of Ions in the Gas Phase

✍ Scribed by H. E. Audier; P. Mourgues; G. van der Rest; J. Chamot-Rooke; H. Nedev


Publisher
John Wiley and Sons
Year
2004
Weight
49 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract The kinetics and the stereochemistry of the protonation‐induced unimolecular isomerization of (__S__)‐(+)‐1‐D~1~‐3‐(__p__‐tolyl)butane have been investigated in the gas phase in the 100–160 °C range. The process leads to the almost exclusive formation of the relevant __meta__ isomer wit