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A predictive model for unimolecular reactions of organic ions

✍ Scribed by Richard D. Bowen; B. Jane Stapleton; Dudley H. Williams


Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
656 KB
Volume
13
Category
Article
ISSN
1076-5174

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πŸ“œ SIMILAR VOLUMES


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The unimolecular decompositions of two isomers of [C&N]+, CH3CH2CH=NH2 and CH3CHzh=CH,, are dis-ed in terms of the potential energy profile over which reaction may be considered to occur. The energy needed to promote slow (metastable) dissociations of either ion is found to be less than that require

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The reactions of metastable CH,-CHCH=bCH, oxonium ions generated by alkyl radical loss from ionized allylic alkenyl methyl ethers are reported aod d i s c d Three main reactions occur, corresponding to expulsion of H,O, C2H,/C0 and CH,O. There is also a very minor amount of C,H, elimination. The mec

A fitting formula for the falloff curves
✍ Peng Zhang; Chung K. Law πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 336 KB

## Abstract A fitting formula is proposed to approximate the falloff curves of the pressure‐ and temperature‐dependent unimolecular reaction rate constants. Compared with the widely used Troe's formula, the present expression has the potential to substantially reduce the computation time in its eva