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Unimolecular Reactions of CF 2 ClCFClCH 2 F and CF 2 ClCF 2 CH 2 Cl: Observation of ClF Interchange

โœ Scribed by Zaluzhna, Oksana; Simmons, Jay G.; Setser, D. W.; Holmes, Bert E.


Book ID
120014055
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
152 KB
Volume
112
Category
Article
ISSN
1089-5639

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Kinetic and thermochemical parameters of
โœ R. A. Taccone; O. Salinovich; E. H. Staricco ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 568 KB

The following reactions: (1, -1) . CF, + CzFSC1 CF&l + ' CzF5 (2) (3) were studied over the temperature ranges 533-687 K, 563-663 K, and 503-613 K for the forward reactions respectively and over 683-763 K, for the back reaction. Arrhenius parameters for chlorine atom transfer were determined re