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Isomerisation of CF2ClCH2Cl and CFCl2CH2F by Interchange of Cl and F Atoms with Analysis of the Unimolecular Reactions of Both Molecules

✍ Scribed by Sarah A. Solaka; Sara E. Boshamer; Caroline L. Parworth; Prof. George L. Heard; Prof. Dr. D. W. Setser; Prof. Bert E. Holmes


Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
533 KB
Volume
13
Category
Article
ISSN
1439-4235

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πŸ“œ SIMILAR VOLUMES


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The rate coefficients for the removal of C1 atoms by reaction with three HCFCs, CF3CHC12 (HCFC-123), CF3CHFCl (HCFC-124), and CH3CFC12 (HCFC 141b), were measured as a function of temperature between 276 and 397 K. CH3CF2C1 (HCFC-142b) was studied only a t 298 K. The Arrhenius expressions obtained ar

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A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.

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## Abstract Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CH~2~FOCH~2~F in 700 Torr of N~2~/O~2~ at 296 K. Relative rate techniques were used to measure __k__(Cl + CH~2~FOCH~2~F) = (4.6 Β± 0.7) Γ— 10^βˆ’13^ and __k__(Cl + CH~2~FOC(O)F) = (2.9 Β± 0.8) Γ— 10^βˆ’15^ (in un

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## Abstract Relative rate experiments using UV photolysis of F~2~ or Cl~2~ have been used to determine rate constant ratios for several hydrofluorocarbon (HFC) reactions with Cl or F atoms and for HFC alkyl radicals with molecular halogens. For mixtures with F~2~ present, dark reactions are, also,

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## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m