Unimolecular Reactions of Chemically Activated CF 2 BrCF 2 CH 3 and CF 2 BrCF 2 CD 3 : Evidence for 1,2-FBr Interchange
โ Scribed by Lisowski, Carmen E.; Duncan, Juliana R.; Heard, George L.; Setser, Donald W.; Holmes, Bert E.
- Book ID
- 127043896
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 108 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 ฯฎ 2 K, have been measured as 0.034 ฯฎ 0.009 for the collision between CF 3 CH 2 CF 2 ฯฉ CF 3 radicals and as 0.075 ฯฎ 0.019 for CF 3 CH 2 CF 2 ฯฉ CF 3 CH 2 CF 2 radicals. The effect of the two fluori
The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine