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Unimolecular metastable decay of molecular clusters ions via monomer-fragment ejection: [(O2)n]−*→[(O2)n−1O]−+O

✍ Scribed by D. Margreiter; G. Walder; Z. Herman; T.D. Märk

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 511 KB
Volume: 167
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)87179-u

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✦ Synopsis

The stability of ( 02); ions produced by electron attachment to a neutral cluster beam has been studied with a double-focusing sector field mass spectrometer. Besides monomer evaporation via metastable dissociation reactions (Oz);*-(Oi);?, t O2 it was possible to observe for the fint time metastable cluster ion dissociations via ejection of a monomer-fragment, i.e. [ (Oi).]-*-[ (02)._,0] -to. Mechanism, dynamics and energetics of this reaction are presented and discussed.

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