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Unimolecular Decay of Metastable Cluster Anions: (O2)N−* → (O2) + O2

✍ Scribed by P. Scheier; T. D. Märk

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 288 KB
Volume: 30
Category: Article
ISSN: 0005-8025
DOI: 10.1002/ctpp.2150300606

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✦ Synopsis

Unimolecular dissociation of metastable excited states of (O,),,-* into (02);-l cluster anions has been detected and studied quantitatively for n in the range of 13 to 22. The apparent metastable (decay rates determinedincrease with cluster size in from -5000 s-l (for n = 13) up to-8 5 0 0 ~-~ for n = 22).

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