Unimolecular decay of metastable ions in formaldehyde
β Scribed by H. Wankenne; G. Caprace; J. Momigny
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 647 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0168-1176
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π SIMILAR VOLUMES
Unimolecular dissociation of metastable excited states of (O,),,-\* into (02);-l cluster anions has been detected and studied quantitatively for n in the range of 13 to 22. The apparent metastable (decay rates determinedincrease with cluster size in from -5000 s-l (for n = 13) up to-8 5 0 0 ~-~ for
The stability of ( 02); ions produced by electron attachment to a neutral cluster beam has been studied with a double-focusing sector field mass spectrometer. Besides monomer evaporation via metastable dissociation reactions (Oz);\*-(Oi);?, t O2 it was possible to observe for the fint time metastabl