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Unifying the solution thermochemistry of molecules, radicals, and ions

✍ Scribed by Griller, David; Martinho Simoes, J. A.; Mulder, P.; Sim, B. A.; Wayner, D. D. M.


Book ID
126469199
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
666 KB
Volume
111
Category
Article
ISSN
0002-7863

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A new estimate is derived for the group additivity contribution AH,"IO-(O),l = 55 2 6 kJ mol ', based upon recent experimental data, which enables heats of formation and bond dissociation energies to be estimated for species RO,,R and RO, (R = H, CH,, and CF,). Semi-empirical MNDO calculated heats o