Reactivity Patterns of Radical Ions—A Unifying Picture of Radical Anion and Radical Cation Transformations
✍ Scribed by Michael Schmittel; Manas K. Ghorai
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 50 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Alkali metal derivatives of organosilicon compounds are useful not only in organosilicon chemistry, but also in organic synthesis. The synthesis, reactivity, and structural aspects of silyllithium compounds are the most studied of alkali metal derivatives. [1] Numerous anionic organosilicon compound
## Abstract The structure and reactivity of the cysteine methyl ester radical cation, CysOMe^.+^, have been examined in the gas phase using a combination of experiment and density functional theory (DFT) calculations. CysOMe^.+^ undergoes rapid ion–molecule reactions with dimethyl disulfide, allyl