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Free-radical and molecule thermochemistry from studies of gas-phase iodine-atom reactions

✍ Scribed by Golden, David M.; Benson, Sidney W.

Book ID
121436881
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
1001 KB
Volume
69
Category
Article
ISSN
0009-2665

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πŸ“œ SIMILAR VOLUMES

Unimolecular gas-phase reactions of the
Unimolecular gas-phase reactions of the methyl acetoacetate radical cation. Oxygen atom permutation via ion-molecule complexes
✍ DorothΓ©e Berthomieu; Jeanine Tortajada; Jean-Pierre Morizur; Henri-Edouard Audie πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 588 KB

The reactions of metastable decomposing methyl acetoacetate (a mixture of keto and enol tautomers) are reported and discussed. The unimolecular fragmentations of the tautomers are different. The metastable decomposing radical cation of the keto form displays four specific ions: [ M -CO] +', IM -CHzO

Kinetics and thermochemistry of the gas-
Kinetics and thermochemistry of the gas-phase reactions of 4-ethylpyridine with OH radical: A DFT study
✍ Kh. Jogeshwari Devi; Asit K. Chandra πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier 🌐 English βš– 460 KB

The gas-phase reaction between 4-ethylpyridine and OH radical are studied using the hybrid density functional model MPWB1K and BB1K methods. Thermochemistry and kinetic parameters for both addition and hydrogen abstraction reaction from all the potential sites are considered. Barrier heights for all