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Unexpected synthesis of 3,5-diethoxycarbonyl-2-pentafluorophenyl-4-phenyl-7,8,9,10-tetrafluoro-4,5-dihydrobenzo[b]oxacin-6-one

โœ Scribed by Yanina V. Burgart; Marina V. Pryadeina; Olga G. Kuzueva; Mikhail I. Kodess; Victor I. Saloutin; Oleg N. Chupakhin


Book ID
119767897
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
95 KB
Volume
11
Category
Article
ISSN
0959-9436

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## Synthesis of 2,4- 6,7,8,9,9methanopyrimido[4,azocine. -Optimization of direct annulation of triaminopyrimidine (I) with cyclohexenone (II) is achieved using acetic acid as solvent in a screw-capped pressure tube that is heated at 120 โ€ข C for 18 hours. Compound (VII) as prototype, its derivative