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Ueber 9.10-Diphenyl-phenanthren

✍ Scribed by Biltz, Heinrich


Publisher
Wiley (John Wiley & Sons)
Year
1905
Weight
195 KB
Volume
38
Category
Article
ISSN
0365-9631

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## Abstract Die Acetolyse des Ditosylats von __trans__‐9.1 0‐Bis‐hydroxymethyl‐9.10‐dihydro‐phenanthren (__trans__‐**5**) in Gegenwart von Natriumacetat (unter kinetischer Kontrolle) führt zu einem Diol mit mittelständigem Sieben‐Ring (__trans__‐**6**) neben dem nicht‐umgelagertem Alkohol __trans__

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## Abstract Treatment of phenanthrene‐9,10‐dione (PQ) with phenanthrene‐9,10‐diol (PQH~2~), as prepared by catalytic hydrogenation of PQ, in toluene solution or in the solid state afforded crystalline ‘9,10‐phenanthrenequinhydrone’ (PQH), the first example of an __ortho__‐quinhydrone. PQH was chara