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Télomérisation du chlorure de vinylidène, 1. Réaction avec le tétrachlorure de carbone par catalyse rédox

✍ Scribed by Belbachir, Mohamed ;Boutevin, Bernard ;Piétrasanta, Yves ;Rigal, Gérard

Publisher
Wiley (John Wiley & Sons)
Year
1984
Weight
582 KB
Volume
185
Category
Article
ISSN
0025-116X

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✦ Synopsis

The redox telomerization of vinylidene chloride with carbon tetrachloride catalyzed by iron or copper salts was thoroughly studied. The DP,, of the telomers obtained vary from 1 to 100, roughly. The concentration of the reactants and the nature of the solvents exert some effect on the molecular weight distribution. The first adducts l a -l d (n = 1 to 4) were isolated and identified by NMR spectroscopy and viscosimetry.

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