The adducts and bi-adducts of the reaction of vinyl chloride with carbon tetrachloride, CC13-(CH,CHCI)n-C1 and CI-(CHClCH,-1,,,-CCl~--(CH~CHCI~CI, respectively, have been studied by '3C and 'H NMR. The identification of the characteristic peaks of each product enables a much better control of the pu
Etude des systèmes binaires formées par le chlorure de cyanogène et par les tétrachlorures de carbone, de silicium, de germanium et d'étain
✍ Scribed by Marie-Hélène Labaye; André Doucet; Roger Perrot; Claude Dubois
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- German
- Weight
- 515 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Study of binary systems formed by cyanogen chloride and the tetrachlorides of carbon, silicon, germanium and tin.
The diagrams of binary mixtures of cyanogene chloride with the tetrachlorides of carbon, silicon, germanium and tin were studied. Only SnCl~4~ gives an addition compound: SnCl~4~ · 2ClCN. The existence of the complex was confirmed by X‐ray diffraction and vapour pressure measurements. This complex gives SnCl~4~ · 2NOCl on treatment with nitrosyl chloride.
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