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Etude des systèmes binaires formées par le chlorure de cyanogène et par les tétrachlorures de carbone, de silicium, de germanium et d'étain

✍ Scribed by Marie-Hélène Labaye; André Doucet; Roger Perrot; Claude Dubois


Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
515 KB
Volume
59
Category
Article
ISSN
0018-019X

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✦ Synopsis


Study of binary systems formed by cyanogen chloride and the tetrachlorides of carbon, silicon, germanium and tin.

The diagrams of binary mixtures of cyanogene chloride with the tetrachlorides of carbon, silicon, germanium and tin were studied. Only SnCl~4~ gives an addition compound: SnCl~4~ · 2ClCN. The existence of the complex was confirmed by X‐ray diffraction and vapour pressure measurements. This complex gives SnCl~4~ · 2NOCl on treatment with nitrosyl chloride.


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