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Two new polymeric chains derived from exo-bidentate binaphthol derivatives

✍ Scribed by Ya-Qiong Gong; You-Fu Zhou; Lei Han; Rui-Hu Wang; Ben-Lai Wu; Ben-Yong Lou; Mao-Chun Hong

Book ID: 103837068
Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 275 KB
Volume: 748
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2005.03.032

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✦ Synopsis

Assembly of CdBr 2 $4H 2 O and 2,2 0 -substituted binol derivatives, (S)-2,2 0 -bis(4-pyridylmethyleneoxy)-1,1 0 -bi-naphthalene [(S)-L], and

In complex 1, chain chirality is from axial chirality of BINOL scaffold. In complex 2, racemic ligands including (S)-L and (R)-L locate in the two sides of the equatorial plane, which suggests the ligand self-discrimination during the assembly process.

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