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Isolation of callipeltins A–C and of two new open-chain derivatives of callipeltin A from the marine sponge Latrunculia sp. A revision of the stereostructure of callipeltins

✍ Scribed by Angela Zampella; Antonio Randazzo; Nicola Borbone; Sisto Luciani; Lucia Trevisi; Cécile Debitus; Maria Valeria D'Auria


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
83 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


Two new callipeltin-related acyclic peptides (2 and 3) have been isolated, together with callipeltins A-C from the marine sponge Latrunculia sp. collected at the Vanuatu Islands. The gross structures of new compounds were elucidated by spectroscopic data. The application of the Marfey's analysis on the new derivatives and on callipeltin A (1), allowed us to revise the configuration of two amino acid units in callipeltin A.


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