New Type of Polymeric Chain Constructed by Exo-bidentate Binaphthol Derivative

✍ Scribed by Ya-Qiong Gong; Lei Han; Rui-Hua Wang; Ben-Yong Lou; Ben-Lai Wu; Mao-Chun Hong

• Book ID: 102097033
• Publisher: John Wiley and Sons
• Year: 2005
• Tongue: English
• Weight: 113 KB
• Volume: 23
• Category: Article
• ISSN: 0256-7660
• DOI: 10.1002/cjoc.200591367

✦ Synopsis

Abstract

The self‐assembly of a racemic exo‐bidentate ligand 2,2′‐bis(4‐pyridylmethyloxy)‐1,1′‐binaphthyl, namely Rac‐L, with cadmium(II) salt gave rise to a new one‐dimensional polymer, which has been characterized by single crystal X‐ray diffraction analysis. The polymer crystallizes in a triclinic space group P‐1 with unit cell parameters: a=0.6976(1) nm, b=1.30160(14) nm, c=1.71146(17) nm,α=105.141(3) °,β=94.263(5)°,γ=100.405(4)°, V=1.4633(2) nm^3^, Z=2, C~32~H~29~CdCl~2~N~2~O~4.5~, M=696.88, D~c~=1.584 g/cm^3^, F(000) =708, μ(Mo Kα) =0.972 mm^−1^. The final R and wR are 0.0498 and 0.1282 for 5079 observed reflections with I≥δ(I).