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Two new open framework cobalt phosphates: NaCo3(OH)(PO4)2.1/4H2O and Na(NH4)Co2(PO4)2.H2O

โœ Scribed by Ranko P Bontchev; Milko N Iliev; Luiz M Dezaneti; Allan J Jacobson

Book ID
114370286
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
349 KB
Volume
3
Category
Article
ISSN
1293-2558

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A new cobalt phosphate Cs 2 Co 3 (HPO 4 )(PO 4 ) 2 ' H 2 O 1, has been synthesized by hydrothermal reactions and characterized by single-crystal X-ray di4raction, thermogravimetric analysis, and magnetic techniques. It crystallizes in the monoclinic space group P2 1 with a โ€ซุโ€ฌ 10.4711 (6) A > , b โ€ซุ