Two new phases, (C 4 H 12 N 2 )(H 3 O)[(VOPO 4 ) 4 (H 2 O)H 2 PO 4 ] ' 3H 2 O (1) and (C 4 H 12 N 2 )[(VO)(VO 2 ) 2 (H 2 O)(PO 4 ) 2 ] (2) have been synthesized hydrothermally and characterized by single crystal X-ray di4raction, thermogravimetric analysis, and magnetic susceptibility. Compound 1 ha
Preparation, Characterization, and Structure of Two Layered Molybdenum(VI) Phosphates: KMo(H2O)O2PO4 and NH4Mo(H2O)O2PO4
β Scribed by Roberto Millini; Angela Carati
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 186 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0022-4596
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2.5 , monoclinic C2/m, a β«Ψβ¬ 18.425(4) A Λ, c β«Ψβ¬ 8.954(2) A Λ, β€ β«Ψβ¬ 93.69(2) 0 , V β«Ψβ¬ 1221.1(4) A Λ3, Z β«Ψβ¬ 4, D calc β«Ψβ¬ 2.423 g cm Ψ3 ; 2 Ψ H 2 O, H 4 F 2 K 2 O 13 P 2 V 3 , triclinic P1, a β«Ψβ¬ 7.298(1) A Λ, b β«Ψβ¬ 8.929(2) A Λ, c β«Ψβ¬ 10.090(2) A Λ, β£ β«Ψβ¬ 104.50(2) 0 , β€ β«Ψβ¬ 100.39(2) 0 , β¦ β«Ψβ¬
A nickel molybdenum phosphate, (NH 3 CH 2 CH 2 NH 3 ) 4 ' (NH 3 CH 2 CH 2 NH 2 ) ' Na ' [Ni 2 Mo 12 O 30 (PO 4 ) (HPO 4 ) 4 (H 2 PO 4 ) 3 ] ' 6H 2 O, involving molybdenum present in V oxidation, has been hydrothermally synthesized and structurally characterized by single crystal X-ray di4raction. De