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Two-dimensional NMR studies of cyperene

✍ Scribed by P. Joseph-Nathan; E. Martińez; R. L. Santillan; J. R. Wesener; H. Günther

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
392 KB
Volume
22
Category
Article
ISSN
0749-1581

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✦ Synopsis

Combined utilization of 'H-IH homonuclear and 'H-l'C heteronuclear N M R chemical shift correlations,

two-dimensional J-resolved 'H NMR measurements and homonuclear 'H double resonance experiments allowed specific assignments for both 'H and -C NMR frequencies to be made for the tricyclic sesquiterpene cyperene. The results also provided information on the conformation of the six-membered ring of this natural product, which was recognized as a distorted chair.

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