Tungsten Carbide by Pyrolysis of Tungsten Hexacarbonyl
โ Scribed by Hurd, Dallas T.; McEntee, H. R.; Brisbin, P. H.
- Book ID
- 126987401
- Publisher
- American Chemical Society
- Year
- 1952
- Weight
- 546 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0019-7866
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๐ SIMILAR VOLUMES
Dime-scartered-wave (DSW) calculations have been performed for the W(CC& molecule. Ground state malecuti orbi-t&, ionization energies, and the lowest d -+ CO rr\* transitions are reported. The results show that relativistic effects stabilize the metal-ligand interaction. but they do not seem to add
Tungsten hexacarbonyl reacts with alkali or tetraalkylammonium halides or pseudohalides MIX (X = halogen or NCS) with elimination of one CO ligand, giving compounds of the type MI[W(CO),X] 121. However, tetraethylammonium azide [31 and W(CO)6 (molar ratio 1 : 15) in diethylene glycol dimethyl ether