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Electronic structure of tungsten hexacarbonyl

✍ Scribed by Cary Y. Yang; Ramiro Arratia-Perez; Jesus P. Lopez

Book ID
103027971
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
432 KB
Volume
107
Category
Article
ISSN
0009-2614

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✦ Synopsis

Dime-scartered-wave (DSW) calculations have been performed for the W(CC& molecule. Ground state malecuti orbi-t&, ionization energies, and the lowest d -+ CO rr* transitions are reported. The results show that relativistic effects stabilize the metal-ligand interaction. but they do not seem to add to the qualitative understanding of the valence electronic StruCtlire. * Supported by US Department of Energy Division of Chemical Sciences through Contract DE-AC03-82ER1301i.

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✍ Priv.-Doz. Dr. W. Beck; Dipl.-Chem. H. S. Smedal πŸ“‚ Article πŸ“… 1966 πŸ› John Wiley and Sons 🌐 English βš– 137 KB πŸ‘ 2 views

Tungsten hexacarbonyl reacts with alkali or tetraalkylammonium halides or pseudohalides MIX (X = halogen or NCS) with elimination of one CO ligand, giving compounds of the type MI[W(CO),X] 121. However, tetraethylammonium azide [31 and W(CO)6 (molar ratio 1 : 15) in diethylene glycol dimethyl ether