The enthalpy of formation of tungsten hexacarbonyl
โ Scribed by D.S. Barnes; G. Pilcher; D.A. Pittam; H.A. Skinner; D. Todd
- Book ID
- 116012361
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 382 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-5088
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Dime-scartered-wave (DSW) calculations have been performed for the W(CC& molecule. Ground state malecuti orbi-t&, ionization energies, and the lowest d -+ CO rr\* transitions are reported. The results show that relativistic effects stabilize the metal-ligand interaction. but they do not seem to add
Tungsten hexacarbonyl reacts with alkali or tetraalkylammonium halides or pseudohalides MIX (X = halogen or NCS) with elimination of one CO ligand, giving compounds of the type MI[W(CO),X] 121. However, tetraethylammonium azide [31 and W(CO)6 (molar ratio 1 : 15) in diethylene glycol dimethyl ether