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Tropolone Biosynthesis: the Enzymatic Decarboxylation of Stipitatonic and Puberulonic Acids

✍ Scribed by BENTLEY, RONALD; THIESSEN, CLARA P.

Book ID
109604723
Publisher
Nature Publishing Group
Year
1959
Tongue
English
Weight
241 KB
Volume
184
Category
Article
ISSN
0028-0836

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Decarboxylative acylation of thiolmalona
Decarboxylative acylation of thiolmalonate. A model for the biosynthesis of fatty acids and polyketides
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In the biosynthesis of fatty acids and polyketides, 1 the malonyl group attached to one of the two sulfhydryl groups (so called "central" SH-group) in the multienzyme complex is decarboxylatively acylated by the acetyl residue attached to the other ("peripheral" SH-group), giving rise to acetothiol