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{Tris[N-(salicylidene)-2-aminoethyl]amine}cobalt(III) acetonitrile hemihydrate

✍ Scribed by Elerman, Y. ;Kabak, M. ;Svoboda, I. ;Geselle, M.

Book ID
114511317
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
332 KB
Volume
50
Category
Article
ISSN
0108-2701

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✍ Schaefer, Michael ;Kurowski, Daniel ;Pfitzner, Arno ;Näther, Christian ;Bensch, 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 368 KB

Yellow crystals of the title compound, [Mn(dien) 2 ][Sb 4 S 7 ]Á-0.5H 2 O (dien = diethylenetriamine = C 4 H 13 N 3 ) were synthesized under solvothermal conditions by reacting MnSb 2 S 4 with pure dien. The Mn 2+ ion is in an octahedral environment of six N atoms of the tridentate dien molecules. T