The title compound, [Sb(C 5 H 10 NO 2 S 2 ) 3 ], has been redetermined at 93 K, allowing a detailed analysis of the crystal packing, which is dominated by O-HÁ Á ÁO hydrogen bonding. Each terminal hydroxyl group participates in a 12-membered [Á Á ÁO-H] 6 ring, leading to a three-dimensional array. m
Tris(ethyldithiocarbamato-κ2S,S′)cobalt(III)
✍ Scribed by Zhang, Gui-Ling ;Li, Yan-Tuan ;Wu, Zhi-Yong
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 118 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the crystal structure of the title compound, [Co(C 3 H 6 NS 3 ) 3 ], the Co II atom lies on a threefold axis; its coordination geometry is distorted octahedral, consisting of six S atoms from three chelating ethyldithiocarbamate ligands. metal-organic papers Acta Cryst. (2006). E62, m350-m351 Zhang et al. [Co(C 3 H 6 NS 2 ) 3 ] m351
📜 SIMILAR VOLUMES
In the title compound, [As{S 2 CN(C 2 H 5 ) 2 } 3 ], the coordination environment of the As atom can be described as a distorted trigonal antiprism.
In the title centrosymmetric complex, [Pd(C 6 H 10 NS 2 ) 2 ], the Pd II atom has a square-planar environment with two dithiocarbamate ligands coordinating through their S atoms in a bidentate chelating fashion.
In the title complex, [Sn(C~7~H~6~Cl)~2~(C~7~H~13~N~2~S~2~)Cl], the Sn atom is five-coordinate in a trigonal–bipyramidal geometry. One Sn—S bond is markedly longer than the other for the chelating dithiocarbamate ligand.