Tris[bis(diphenylphosphino)methane-κ2P,P′]rhenium(I) perrhenate
✍ Scribed by Whitmire, Kenton H. ;Derringer, Daniel R. ;Kongkasuwan, Kimberly R.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 173 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.020 A Ê Disorder in main residue R factor = 0.046 wR factor = 0.115 Data-to-parameter ratio = 19.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The title " 3 -Cl dicapped trisilver compound, [Ag 3 Cl 2 -(C 25 H 22 P 2 ) 3 ][SbF 6 ]Á2CH 2 Cl 2 , exhibits distorted trigonal bipyramidal coordination with two " 3 -Cl atoms at the apices. The Ag I atoms are four-coordinated and exhibit a tetrahedral geometry.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.020 A Ê R factor = 0.034 wR factor = 0.096 Data-to-parameter ratio = 16.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.
Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.012 A Ê R factor = 0.082 wR factor = 0.234 Data-to-parameter ratio = 20.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.