Tris(bipyridyl)ruthenium(II)-photosensitized reaction of 1-benzyl-1,4-dihydronicotinamide with benzyl bromide
✍ Scribed by Hironaka, Katsuhiko; Fukuzumi, Shunichi; Tanaka, Toshio
- Book ID
- 119975954
- Publisher
- Royal Society of Chemistry
- Year
- 1984
- Tongue
- English
- Weight
- 563 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1472-779X
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📜 SIMILAR VOLUMES
02139 (R8ceived in IJR 12 Cctober 1972; acoepted for publication 26 Octobar 1972) le would like to report the dimerization of I-benzyl-1,4-dihydronicotinamide in acidic aqueous suspension to form the polycyclic cage molecule 1 in high yield. Although
## Abstract The photoinduced reaction of a mixture of (Z)‐α‐cyano‐β‐bromomethylcinnamide (1) and (__E__)‐α‐cyano‐β‐bromomethylcinnamide (2) with 1‐benzyl‐1, 4‐dihydronicotinamide produces a mixture of the (__E__)‐ and (__Z__)‐ isomers of α‐cyano‐β‐methylcinnamide (3 and 4). Using spin‐trapping tech
Reduction of alkylmercury(I1) acetates with N-benzyl-1,4\_dihydronicotin amide (BNAH) proceeds through electron-transfer chain-substitution mechanism. The rate constant of hydrogen transfer from BNAH to alkyl radical was estimated as in the order of lo5 l/mol.sec. There is much current interest bo