✦ LIBER ✦

Electron-transfer chain-substitution in hydrodemercuration of alkylmercury(II) compounds with n-benzyl-1,4-dihydronicotinamide

✍ Scribed by Hideo Kurosawa; Hiroshi Okada; Tatsuaki Hattori

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 216 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93024-2

No coin nor oath required. For personal study only.

✦ Synopsis

Reduction of alkylmercury(I1) acetates with N-benzyl-1,4_dihydronicotin amide (BNAH) proceeds through electron-transfer chain-substitution mechanism.

The rate constant of hydrogen transfer from BNAH to alkyl radical was estimated as in the order of lo5 l/mol.sec.

There is much current interest both in exploring the range of substrates and elucidating the mechanism in the reduction of inorganic and organic compounds with 1,4_dihydropyridine derivatives.

Recent studieslt2 demonstrated that these reductants can be used more suitably than metal hydrides in hydrogenating certain organic substrates such as nitro and sulfonium compounds.

📜 SIMILAR VOLUMES

Reactions of organo-thallium(III) and -m

Reactions of organo-thallium(III) and -mercury(II) compounds with nitronate ion and N-benzyl-1,4-dihydronicotinamide: reductive electron-transfer activation of the metal-carbon bond toward homolysis

✍ H. Kurosawa; H. Okada; M. Sato; T. Hattori 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 53 KB

Thermotropic liquid crystalline compound

Thermotropic liquid crystalline compounds with lateral long-chain substituents (II).: Synthesis and liquid crystalline properties of 1,4-Bis [4-substituted-benzoyloxy]-2-n-alkylbenzenes

✍ Dr. W. Weissflog; Prof. Dr. D. Demus 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 367 KB 👁 1 views